Pericyclic additions
Hi, every one
There are two recent papers of contradictory opinions on the mechanism
of
Diels-Alder reactions if you are interested:
1. Tetrahedron Lett. 2001, 42, 5077. ?Merging of 4+2 and 2+4
cycloadditon
paths in the regiospecific dimerization of methacrolein. A case of
concerted
crypto-diradical cycloaddition?
2. http://preprint.chemweb.com/orgchem/0107002
?Collision-induced electron reorganization as the general mechanism
of
concerted cycloaddition reactions?.
Yuan-Yuan
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