From owner-chemistry@ccl.net Thu Sep 8 21:14:01 2016 From: "Muhammad Abduh Nasution abduh a mhs.unimed.ac.id" To: CCL Subject: CCL: HOMO energy and redox potential Message-Id: <-52374-160908211152-1477-E/2kdxRdWHyZwKi/UaeVRg||server.ccl.net> X-Original-From: Muhammad Abduh Nasution Content-Type: multipart/alternative; boundary=001a11439ef22b6186053c08d4ce Date: Fri, 9 Sep 2016 08:11:40 +0700 MIME-Version: 1.0 Sent to CCL by: Muhammad Abduh Nasution [abduh^mhs.unimed.ac.id] --001a11439ef22b6186053c08d4ce Content-Type: text/plain; charset=UTF-8 Hi Adam, Thanks very much for your answer. Previously I've plot it with r^500 on MS Excel and I find for higher order exponent it's R squared is higher. Let me explain the background. From collision theory equation, I think it is similiar to volumetric flow rate equation. So I try to derive volumetric flow rate equation to obtain reaction rate equation. I found equation k = ('ain x Ek)/(Mr x r^5) where k= reaction rate constant, 'ain = coefficient, Ek = kinetic energy, Mr = relative mass, r = radius. So I plot k from this equation with ionization potential as HOMO energy. On the other hands, I think Arrhenius equation and Eyring equation has similiarity to this problem, because reaction rate constant is exponential of energy form. Correct me if I'm wrong. Best, Muhammad Abduh --001a11439ef22b6186053c08d4ce Content-Type: text/html; charset=UTF-8 Content-Transfer-Encoding: quoted-printable Hi Adam,
Thanks very much for your answer. Previously I've plot it w= ith r^500
on MS Excel and I find for higher order exponent it's R sq= uared is
higher.
Let me explain the background. From collision theory= equation, I think
it is similiar to volumetric flow rate equation. So I= try to derive
volumetric flow rate equation to obtain reaction rate equ= ation. I
found equation k =3D ('ain x Ek)/(Mr x r^5)
where k=3D r= eaction rate constant, 'ain =3D coefficient, Ek =3D kinetic
energy, = Mr =3D relative mass, r =3D radius. So I plot k from this equation
with = ionization potential as HOMO energy.
On the other hands, I think Arrheni= us equation and Eyring equation has
similiarity to this problem, because= reaction rate constant is
exponential of energy form.
Correct me if = I'm wrong.
Best,


Muhammad Abduh --001a11439ef22b6186053c08d4ce--