From chemistry-request#* at *#server.ccl.net Fri Jan 7 17:17:47 2000 Received: from igor.wag.caltech.edu (igor.wag.caltech.edu [131.215.33.3]) by server.ccl.net (8.8.7/8.8.7) with ESMTP id RAA02458 for ; Fri, 7 Jan 2000 17:17:47 -0500 Received: from wag.caltech.edu (octane2 [131.215.33.125]) by igor.wag.caltech.edu (8.9.3/8.9.3) with ESMTP id OAA141222 for ; Fri, 7 Jan 2000 14:16:48 -0800 (PST) Sender: rpm "-at-" wag.caltech.edu Message-ID: <387665CF.C75457F8: at :wag.caltech.edu> Date: Fri, 07 Jan 2000 14:16:47 -0800 From: "Richard P. Muller" X-Mailer: Mozilla 4.6 [en] (X11; U; IRIX64 6.4 IP30) X-Accept-Language: en MIME-Version: 1.0 To: chemistry%!at!%ccl.net Subject: Pekeris Technique for 2-electron Atoms References: Content-Type: text/plain; charset=us-ascii Content-Transfer-Encoding: 7bit I'm currently working on 2-electron atoms using Pekeris' approach (see Phys Rev 112, 1649 (1958) and Phys Rev 115, 1216 (1959)). I believe that Equation 22 of the 1958 paper has an error in it, because the results don't agree with the special case results for the 7x7 case that Pekeris puts on the following page of that paper. I've checked my work several times, but there still appears to be something wrong. I looked for, but did not find, a published errata for this paper, which concerns me, since they've certainly had time to get a correction out, so I could be doing something dumb. Has anyone else worked through this paper? If so, could they offer me any help. Thanks very much in advance. Rick Muller