%mem=128MB
%chk=S_PdCNCH.chk
#P mPW1PW91/GEN PSEUDO=Cards GEOM=Check GUESS=Read OPT SCF=(MaxCycle=1024) 
SCRF=(IEFPCM,Read)

Pd(L)(H) (L=bis(l-imidazolyl)-pyridine dicarbene)

1 1

Pd 0
 S    3 1.00
  0.2787000000D+01 -0.1610239000D+01
  0.1965000000D+01  0.1848984000D+01
  0.6243000000D+00  0.6037492000D+00
 S    4 1.00
  0.2787000000D+01  0.1354078000D+01
  0.1965000000D+01 -0.1678085000D+01
  0.6243000000D+00 -0.8559381000D+00
  0.1496000000D+00  0.1020030000D+01
 S    1 1.00
  0.4360000000D-01  0.1000000000D+01
 P    3 1.00
  0.5999000000D+01 -0.1034910000D+00
  0.1443000000D+01  0.7456952000D+00
  0.5264000000D+00  0.3656494000D+00
 P    4 1.00
  0.5999000000D+01  0.2670153000D-01
  0.1443000000D+01 -0.2457828800D+00
  0.5264000000D+00 -0.1426049000D-01
  0.8990000000D-01  0.7898110300D+00
 P    1 1.00
  0.2620000000D-01  0.1000000000D+01
 D    3 1.00
  0.6091000000D+01  0.3761460000D-01
  0.1719000000D+01  0.5200479000D+00
  0.6056000000D+00  0.5706071000D+00
 D    1 1.00
  0.1883000000D+00  0.1000000000D+01
 F   1  1.00
      1.472000000          1.00000000
****
C N 0
6-31G(d')
****
18 19 20 21 22 23 24 25 26
6-31G(d')
****
27
6-31G(d',p')
****

Pd 0
LANL2DZ

rsolv=3.93 eps=38.93 nodis nocav
dump