calculating atomic charges with AIMPAC



I currently have an undergraduate student who is attempting to compare charges of methylated benzene and ferrocene systems using the AIMPAC software. In the case of hexamethyl benzene and the ferrocene analogues he is getting very large negative charges on some the ring carbons (-5 to -20) and small positive charges on iron (0.5) Can anyone tell me if there is a problem with the program or if the ring system can not be treated with this method?
 Thank you,
 Julia Metzker
 University of York
 Department of Chemistry